水热合成
反铁磁性
铁磁性
链条(单位)
热液循环
材料科学
磁化率
结晶学
理想(伦理)
凝聚态物理
变质磁性
纳米技术
化学
量子
立体化学
磁场
磁畴
订单(交换)
化学物理
替代(逻辑)
手性(物理)
作者
Du Wang,Meiyan Cui,Wenhao Zhang,Tianyu Zhu,Zhiying Zhao,Zhangzhen He
标识
DOI:10.1021/acs.cgd.6c00848
摘要
Abstract One-dimensional kagomé strip chain (KSC) systems are ideal platforms for studying geometrical frustration; however, their experimental explorations remain extremely scarce. Herein, we report the hydrothermal synthesis of a new KSC compound, Ag2Cu5(TeO3)(SO4)3(OH)4. Magnetic measurements indicate that this compound possesses a long-range antiferromagnetic order at TN = 3.6 K and exhibits a dominant ferromagnetic interaction in the system (θcw = +20.1 K), where field-induced metamagnetic transition can be observed under an applied magnetic field. The structural and magnetic comparisons with the Na/K analogues are also performed. The present results enrich the KSC family and show a cation-substitution effect in such quantum magnetic systems.
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