Enhancing carrier collection in CsPbBr3 solar cells through crystal orientation and defect passivation

All-inorganic carbon-based CsPbBr3 perovskite solar cells (PSCs) have gained growing interest for their remarkable stability. However, compared to their organic–inorganic hybrid counterparts, there is still substantial room for improving their performance primarily due to the inferior photogenerated carrier collection efficiency. Here, we employ area-dependent transient photocurrent to assess the carrier transit time in CsPbBr3 PSCs, revealing that an extended carrier transit time relative to the lifetime significantly contributes to their low carrier collection efficiency. To address this challenge, we narrow the gap between carrier transit time and lifetime by introducing a dual-functional additive, serving to facilitate both crystallization orientation and defect passivation. Consequently, we achieve enhanced short-circuit current and efficiency in CsPbBr3 PSCs.