化学
均分解
键裂
激进的
光化学
催化作用
光催化
惰性
烷基
有机合成
偶联反应
劈理(地质)
过渡金属
有机化学
光催化
工程类
岩土工程
断裂(地质)
标识
DOI:10.1002/ejoc.202201139
摘要
Over the past decade with the relaunch of photochemistry, photochemical cross-coupling reactions became an excellent tool for the formation of C-C bond under mild reaction conditions. Csp3-H functionalization of inert substrates, combined with modern transition metal catalysis, provides a powerful tool in organic synthesis. A variety of elegant strategies to initiate a HAT event have been developed, generating alkyl radicals that can be easily intersected with a metal. This review conceptualizes the recent developments in this area, linking them with the seminal contributions that pioneered this research field.
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