阳离子聚合
光化学
发光
部分
吡啶
咔唑
化学
接受者
聚集诱导发射
电子供体
肉眼
材料科学
高分子化学
立体化学
药物化学
荧光
有机化学
光电子学
催化作用
凝聚态物理
物理
检出限
量子力学
色谱法
作者
Kai-Yue Zhao,Weilin Song,Yang Yang,Ying-Chen Duan,Guangfu Li,Guo‐Gang Shan,Qiang Fu,Zhong‐Min Su
标识
DOI:10.1016/j.dyepig.2020.108817
摘要
Three new cationic Ir(III) complexes with donor-acceptor (D-A) type ligands, in which a 2-(1H-tetrazol-5-yl)pyridine unit as an electron acceptor and carbazole-based functional moiety as an electron donor, namely Ir-TA-CzDBr, Ir-TA-CzBr and Ir-TA-Cz, are synthesized and characterized. All complexes exhibit obvious aggregation-induced emission (AIE) activities with weak emission in diluted solution but bright light in the aggregation state. The present AIE mechanism was also elucidated by performing the comprehensive theoretical calculation. Moreover, the Ir(III) complexes show excellent reversible mechanochromic luminescent (MCL) behaviors and the emission colors in powder can be switched by grinding and fuming. The reversible, naked-eye visible and efficient mechanochromism of designed Ir(III) complexes paves the way toward the potential application in the field of reversible writing/erasing paper.
科研通智能强力驱动
Strongly Powered by AbleSci AI