氧化剂
催化作用
化学
漆酶
甲烷氧化偶联
原位
氧化磷酸化
组合化学
有机化学
酶
生物化学
作者
Ehdieh Khaledian,Amin Rostami,Seyed Amir Zarei
标识
DOI:10.1016/j.catcom.2018.06.007
摘要
The first report on aerobic in situ generation and regeneration of N-phenyltriazolinedione, a valuable oxidizing agent, from a catalytic amount of N-phenyl urazole in the presence of a laccase enzyme is presented. The application of a 4-phenyl urazole/Laccase/O2 as a new cooperative catalytic oxidation system is reported for a transition-metal-free and halogen free oxidative homo-coupling reaction of structurally diverse thiols to their corresponding disulfides with good to excellent yields in a phosphate buffer solution under mild reaction conditions.
科研通智能强力驱动
Strongly Powered by AbleSci AI