材料科学
傅里叶变换红外光谱
亚甲蓝
催化作用
复合数
聚苯乙烯
核化学
纳米颗粒
扫描电子显微镜
分散聚合
化学工程
聚合
光催化
纳米技术
复合材料
化学
有机化学
聚合物
工程类
作者
Yang Liu,Liu T,Xiangchi Liu,Baijun Liu,MingYao Zhang
摘要
Abstract In this research, monodispersed polystyrene (PS) microspheres were prepared by dispersion polymerization. PS microspheres decorated with silver nanoparticles (PS/Ag composite microspheres) were synthesized by a modified chemical plating method with water as the synthesis medium. The microspheres at each stage were characterized by Fourier transform infrared spectroscopy (FTIR), X‐ray diffraction (XRD), UV–visible spectroscopy (UV–vis), field‐emission scanning electron microscopy (FESEM), and energy‐dispersive spectrometer (EDS). The reduction of methylene blue (MB) was carried out with PS/Ag composite microspheres as a catalyst and NaBH 4 as a reducing agent. The results showed that the MB dye was reduced to colorless within 180 s. The reduction of the MB dye followed pseudo‐first‐order kinetics with an apparent rate constant (K app ) value of 0.01425 s −1 . Control experiments were also carried out by adding microspheres from each chemical plating pretreatment stage to the MB, without PS/Ag composite microspheres. The catalytic activity of the PS/Ag composite microspheres was high after five consecutive cycles of recovery, showing promising reusability. The catalytic activity of the prepared PS/Ag catalysts was superior to other catalysts for the reduction of MB.
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