Recent Developments in Amine‐catalyzed Non‐asymmetric Transformations

Abstract Amine catalysis has emerged as a powerful and elegant method to construct diverse chiral scaffolds in asymmetric synthesis. However, amine‐based non‐asymmetric organocatalysis is still in its infancy. This Focus Review examines recent developments in amine‐catalyzed non‐asymmetric transformations based on enamine, iminium, di‐ or trienamine, and oxidative enamine catalysis.