电解质
水溶液
离子
储能
材料科学
纳米技术
化学
电极
化学工程
工艺工程
热力学
工程类
有机化学
功率(物理)
物理
物理化学
作者
Hongfei Bao,Hele Guo,Xuan Zhang,Zhihong Tian,Jiajia Huang,Tianxi Liu,Feili Lai
标识
DOI:10.1002/tcr.202300212
摘要
Aqueous rechargeable multivalent metal-ion batteries (ARMMBs) have attracted considerable attention due to their high capacity, high energy density, and low cost. However, their performance is often limited by low temperature operation, which requires the development of anti-freezing electrolytes. In this review, we summarize the anti-freezing mechanisms and optimization strategies of anti-freezing electrolytes for aqueous batteries (especially for Zn-ion batteries). Besides, we investigate the possible interactions and side reactions between electrolytes and electrodes. We also analyze the problems between electrolytes and electrodes at low temperature, and propose possible solutions. The research progress in the field of low temperature energy storage for aqueous Mg-ion, Ca-ion, and Al-ion batteries, and the challenges faced in their anti-freezing electrolytes are investigated in detail. Last but not least, the outlook on the energy storage applications of ARMMBs is provided to guide the future research.
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