Bioinspired, Ultra‐Fast Polymerization of Dopamine under Mild Conditions

Spontaneous oxidative polymerization of dopamine (DA) is widely exploited as a facile and versatile method for surface modification. However, the reaction is very slow and only occurs in alkaline solutions, which severely limit its applications. Herein it is reported that the reaction can be dramatically accelerated by using Fe²⁺ as catalyst. While it takes hours and days using conventional method, the Fe²⁺ -catalyzed reaction finishes almost immediately at pH 7.0. In addition, under the catalysis of Fe²⁺ , the reaction can occur at a pH down to 4.0. The fast Fe²⁺ -catalyzed polymerization of DA leads to fast deposition of polydopamine (PDA) coating, thus allowing fast surface modification and textile dyeing. The Fe²⁺ -catalyzed reaction also allows spatial control over the PDA deposition. The fast, simple, and mild surface modification method developed here will find applications in numerous fields.