微型多孔材料
碳化
材料科学
化学工程
吸附
碳纤维
氢
生物量(生态学)
比表面积
氢气储存
木质素
X射线光电子能谱
核化学
化学
有机化学
催化作用
复合材料
复合数
海洋学
工程类
地质学
作者
Fangyi Cheng,Jing Liang,Jianzhi Zhao,Zhanliang Tao,Jun Chen
摘要
We report on the facile preparation of biomass waste-derived microporous carbons and the investigation of their hydrogen storage performance. By adjusting the reaction parameters, different carbon materials with controlled morphology and texture were prepared through the carbonization and activation of the hydrolytic lignin from inexpensive biomass waste. The as-obtained samples were characterized using instrumental analyses such as SEM, TEM, EDX, XRD, IR, ICP, and XPS. It was found that the as-synthesized microporous carbons exhibited high surface area (2000−3100 m2 g−1), large micropore volume (1.11−1.68 cm3 g−1), and narrow pore size distribution (0.77−0.91 nm). Furthermore, a considerable hydrogen uptake exceeding 5 wt % with an isosteric adsorption heat of 4.1−7.5 kJ mol−1 was attained with the microporous carbons, showing their potential usage in compacting gaseous fuels of hydrogen.
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