合成子
砜
试剂
化学
组合化学
催化作用
嵌入
简单(哲学)
有机化学
计算机科学
人工智能
认识论
哲学
作者
Xianglong Chen,Chunyan Wu,Jin‐Tian Ma,Shi‐Yi Zhuang,Zhi‐Cheng Yu,Yan‐Dong Wu
出处
期刊:Organic Letters
[American Chemical Society]
日期:2021-12-16
卷期号:24 (1): 223-227
被引量:34
标识
DOI:10.1021/acs.orglett.1c03877
摘要
Rongalite has been used in several challenging synthetic transformations with operationally simple and effective protocols. However, the employment of multiple characteristics of rongalite in synthetic chemistry is comparatively little known. Herein we report a separate-embedding type sulfonylmethylation of sulfoxonium ylides in which rongalite concurrently acted as a sulfone source, C1 synthon, radical initiator, and potential reducing reagent for the first time. Notably, this facile and easy-handling reaction does not require a catalyst or prefunctionalized sulfonylmethylation reagents.
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