燃烧
等离子体
燃烧室
氨
旋转温度
电子密度
当量比
分析化学(期刊)
发射光谱
强度(物理)
材料科学
发射强度
温度电子
电弧
原子物理学
化学
谱线
离子
光学
电极
环境化学
物理化学
分子
物理
有机化学
天文
量子力学
作者
Xi-Ming Zhu,Yang Zhao,Ming Zhai,Pengyi Lv,Weixing Zhou,Bangdou Huang
出处
期刊:Processes
[Multidisciplinary Digital Publishing Institute]
日期:2022-09-02
卷期号:10 (9): 1750-1750
被引量:23
摘要
Ammonia as a non-carbon fuel is expected to play an important role in the future, but it is difficult to be effectively utilized at this stage due to its flame retardancy and other characteristics. Therefore, we propose to use gliding arc plasma combined with a swirl burner to enhance the combustion performance of ammonia. The electrical characteristics, electron density, gas rotational temperature and the distribution of key active species in the burner were studied via optical emission spectroscopy (OES). With the increase of equivalence ratio (EQR), the width of the Hα line decreases significantly, indicating that the electron density shows a downward trend, even as the gas rotational temperature shows an upward trend. When the equivalence ratio was 0.5, the gas rotational temperature increases by about 320 K compared with the pure air condition. During pure air discharge, there will still be obvious NO emission due to the plasma reaction, but with the addition of NH3, the NO content in the emission is significantly reduced. The light intensity of O atoms in the burner gradually decreases with the increase of the equivalence ratio, the light intensity of H atoms increases first and then decreases, and the light intensity of NH shows an upward trend. The reason may be that the plasma discharge effectively strengthens NH3(E)->NH2+H, NH2+H->NH+H2 and other reactions promote the initial reaction step of NH3 which thus effectively strengthens the NH3 combustion.
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