Preface. Fundamentals of Nuclear Magnetic Resonance: Introduction. Nuclear Spin and the NMR Phenomenon. Detection of the Resonance Phenomenon. Nuclear Relaxation. Magnetic Shielding and the Chemical Shift. Indirect Coupling of Nuclear Spins. Rate Phenomena: Averaging of Chemical Shifts and JCouplings. Experimental Methods. The Microstructure of Polymer Chains: Introduction. Polymer Microstructure. Configurational Statistics and Propagation Mechanism. Propagation Errors. The Solution Characterization of Polymers: Introduction. Resonances Assignments. Microstructural Characterization of Polymers in Solution. The Solution Structure of Polymers. The Solid-State NMR of Polymers: Introduction. Chain Conformation in the Solid State. The Organization of Polymers in the Solid-State. NMR Imaging of Polymers. The Dynamics of Macromolecules: Introduction. Polymer Dynamics in Solution. Polymer Dynamics in the Solid State. Subject Index.