化学
Negishi偶联反应
杂原子
试剂
有机合成
锆
双金属片
烷基
有机化学
碳纤维
组合化学
催化作用
复合材料
复合数
材料科学
作者
Chao Jiang,Xiangbing Qi,Chao Yang
出处
期刊:Synthesis
[Thieme Medical Publishers (Germany)]
日期:2021-02-11
卷期号:53 (06): 1061-1076
被引量:11
标识
DOI:10.1055/s-0040-1706146
摘要
Abstract Organozirconium chemistry has found extensive applications in organic synthesis since its discovery in the last century. Alkylzirconocenes, which are easily generated by the hydrozirconation of alkenes with the Schwartz reagent, are widely utilized for carbon–carbon and carbon–heteroatom bond formation. This short review summarizes the progress to date on the applications alkylzirconocenes in organic synthesis. 1 Introduction 2 General Methods for Generating Alkylzirconocenes 3 Transformations of Alkylzirconocenes by Heteroatoms 4 Insertion of Unsaturated Groups into Alkylzirconocenes 5 Transmetalations 6 Cross-Coupling Reactions of Alkylzirconocenes 7 Photochemistry of Alkylzirconocenes 8 Bimetallic Reagents of Zirconium 9 Asymmetric Transformations 10 Applications of Alkylzirconocenes Generated from the Negishi Reagent 11 Conclusions and Outlook
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