磷光
材料科学
合理设计
发光
纳米技术
光电子学
荧光
物理
量子力学
作者
Zhiqiang Yang,Haichao Liu,Xiangyu Zhang,Yingbo Lv,Zhiyuan Fu,Shuaiqiang Zhao,Meng Li,Shitong Zhang,Bing Yang
标识
DOI:10.1002/adma.202306784
摘要
A rational molecular design strategy facilitates the development of a purely organic room-temperature phosphorescence (RTP) material system with precisely regulated luminescence properties, which surely promotes its functional integration and intelligent application. Here, a functional unit combination strategy is proposed to design novel RTP molecules combining a folding unit with diverse luminescent cores. The different luminescent cores are mainly responsible for tunable RTP properties, while the folding unit contributes to the spin-orbit coupling (SOC) enhancement, which makes the RTP material design as workable as the building block principle. By this strategy, a series of color/lifetime-tunable RTP materials is achieved with unique photo-responsive RTP enhancement when subjected to UV irradiation, which expands their application scenarios in reusable privacy tags, advanced "4D" encryption, and phase separation analysis of blended polymers. This work suggests a simple and effective strategy to design purely organic RTP materials with tunable color and lifetime, and also provides new application options for photo-responsive dynamic RTP materials.
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