甲烷
商品化学品
合成气
催化作用
太阳能
甲醇
碳氢化合物
天然气
材料科学
化学
化学工程
纳米技术
有机化学
工程类
电气工程
作者
Guangbo Chen,Geoffrey I. N. Waterhouse,Run Shi,Jiaqing Zhao,Zhenhua Li,Li‐Zhu Wu,Chen‐Ho Tung,Tierui Zhang
标识
DOI:10.1002/anie.201814313
摘要
Abstract Catalytic C 1 chemistry based on the activation/conversion of synthesis gas (CO+H 2 ), methane, carbon dioxide, and methanol offers great potential for the sustainable development of hydrocarbon fuels to replace oil, coal, and natural gas. Traditional thermal catalytic processes used for C 1 transformations require high temperatures and pressures, thereby carrying a significant carbon footprint. In comparison, solar‐driven C 1 catalysis offers a greener and more sustainable pathway for manufacturing fuels and other commodity chemicals, although conversion efficiencies are currently too low to justify industry investment. In this Review, we highlight recent advances and milestones in light‐driven C 1 chemistry, including solar Fischer–Tropsch synthesis, the water‐gas‐shift reaction, CO 2 hydrogenation, as well as methane and methanol conversion reactions. Particular emphasis is placed on the rational design of catalysts, structure–reactivity relationships, as well as reaction mechanisms. Strategies for scaling up solar‐driven C 1 processes are also discussed.
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