超共轭
旋转(数学)
质子
化学
联轴节(管道)
互变异构体
群(周期表)
分子
传输(计算)
化学物理
计算化学
甲基
立体化学
物理
计算机科学
量子力学
材料科学
有机化学
冶金
并行计算
人工智能
作者
Hiroshi Ushiyama,Kazuo Takatsuka
标识
DOI:10.1002/anie.200461459
摘要
Coupling drives the rotation: A theoretical study of proton-transfer dynamics of 5-methyltropolone (5MTR) has identified a long-range mechanical interaction. Methyl group rotation can be driven by proton transfer because of coupling between hyperconjugation and tautomerization within 5MTR (see HOMO–LUMO interaction). A quantum-mechanical mechanism is presented in which this molecule undergoes a conformational change. Supporting information for this article is available on the WWW under http://www.angewandte.org or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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