Will Vanadium‐Based Electrode Materials Become the Future Choice for Metal‐Ion Batteries?

Metal-ion batteries have emerged as promising candidates for energy storage system due to their unlimited resources and competitive price/performance ratio. Vanadium-based compounds have diverse oxidation states rendering various open-frameworks for ions storage. To date, some vanadium-based polyanionic compounds have shown great potential as high-performance electrode materials. However, there has been a growing concern regarding the cost and environmental risk of vanadium. In this Review, all links in the industry chain of vanadium-based electrodes were comprehensively summarized, starting with an analysis of the resources, applications, and price fluctuation of vanadium. The manufacturing processes of the vanadium extraction and recovery technologies were discussed. Moreover, the commercial potentials of some typical electrode materials were critically appraised. Finally, the environmental impact and sustainability of the industry chain were evaluated. This critical Review will provide a clear vision of the prospects and challenges of developing vanadium-based electrode materials.