Dynamic Antisolvent Engineering for Spin Coating of 10 × 10 cm2 Perovskite Solar Module Approaching 18%

Perovskite solar cells represent a promising photovoltaic technology, which achieves record power conversion efficiencies over 24%. However, a problem on the commercial processing is the unavoidable efficiency loss during the scalable fabrication of perovskite solar module. The efficient and reliable fabrications of high‐quality large‐area perovskite films guarantee commercialized up‐scaling of perovskite solar cells with high efficiency. Herein, a simple dynamic antisolvent quenching (DAS) process is presented to understand large‐area uniform perovskite films to obtain an efficient perovskite solar module. This method provides a facile and universal approach to fabricate cracks‐free and uniform large‐area mixed‐cation perovskite films. A champion module device (10 × 10 cm 2 ) with efficiency of 17.82% (another module with certified efficiency of 17.4%) is obtained using DAS process.