共晶体系
电动势
锑
相图
锂(药物)
热力学
电动势测量
材料科学
电化学
合金
电化学电池
电极
相(物质)
冶金
化学
物理化学
电气工程
物理
工程类
内分泌学
有机化学
医学
电解质
作者
Margaret Kane,Jocelyn M. Newhouse,Donald R. Sadoway
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2014-12-31
卷期号:162 (3): A421-A425
被引量:30
摘要
The variation in the high temperature thermodynamic properties of the Li-Sb system with temperature (425–775ºC) and composition (xLi = 0.01–0.75) was determined by electromotive force (emf) measurements in a cell configured as follows: Li-Bi reference electrode (xBi = 0.35) | eutectic of LiCl-KCl or LiCl-LiF | Li-Sb alloy. On the basis of these data the Li-Sb couple was deemed attractive for storage of electrical energy in a liquid metal battery. In addition, an updated Li-Sb binary phase diagram is proposed.
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