Transparent and Flexible Amphiphobic Coatings with Excellent Fold Resistance via Solvent-Free Coating and Photocuring of Fluorinated Liquid Nitrile–Butadiene Rubber

Amphiphobic surfaces have been developed for various applications. However, the harsh construction conditions and multistep processes limit their practical application. Especially for those with a particular surface roughness and morphology, the amphiphobic property might provide a slight deformation. Here, a facile large-area construction of transparent and flexible amphiphobic coatings with excellent fold resistance has been established by simple casting of the fluorinated liquid nitrile–butadiene rubber (F-LNBR) followed by solvent-free photocuring. It was found that the fluorocarbon groups could concentrate onto the coating surface during the UV-induced photocuring. With a certain coating amount, a stable oleophobic coating was achieved with static contact angles of about 95° and 111° for nonpolar oil (n-hexadecane) and polar oil (diiodomethane). Most importantly, the static contact angles of water and diiodomethane of the amphiphobic coatings on the iron sheet increased after bending and remained around 131° and 120° after being completely folded in half for 100 cycles because the inner fluorocarbon groups could be squeezed out from the flexible cross-linked rubber matrix as a reservoir. Such features indicated the promising self-cleaning and surface protection of the proposed transparent and flexible amphiphobic coatings for deformable substrates.