Coupling Effects of CO 2 and Thermal Treatment on the Rheological Behavior of Heavy Oil: An Integrated Experimental and Modeling Study

触变性 流变学 材料科学 阿累尼乌斯方程 热的 剪切(地质) 剪切速率 粘度 剪切减薄 联轴节(管道) 热力学 牛顿流体 抗剪强度(土壤) 流变仪 非牛顿流体 表观粘度 表征(材料科学) 机械 提高采收率 磁滞 石油工程
作者
Qihang Li,Yiqiang Li,Chaoye Yuan,Zheyu Liu,Zhipeng Wang,Jinxin Cao,Yaqian Zhang
出处
期刊:ACS omega [American Chemical Society]
卷期号:10 (48): 59642-59654
标识
DOI:10.1021/acsomega.5c09369
摘要

High Resolution Image Download MS PowerPoint Slide The rheological behavior of high-viscosity heavy oil is crucial for its efficient development. CO 2 -assisted thermal recovery serves as an effective method to enhance heavy oil mobility. However, existing studies still lack sufficient quantitative characterization of the coupling effect of thermal and CO 2 interactions on improving heavy oil flow capacity. To address this issue, this study thoroughly investigates the synergistic viscosity reduction mechanism and the evolution of rheological properties during heavy oil extraction under combined CO 2 and thermal effects. Through systematic rheological testing and theoretical modeling, a modified Arrhenius model incorporating a shear correction factor was developed, enabling accurate prediction of the viscosity–temperature relationship under different shear rates. Dual hysteresis loop analysis was employed to quantify the effects of thermal and shear history, confirming that the thixotropic recovery capability of heavy oil is governed by both thermal and shear history and revealing an exponential decay pattern of thixotropic strength with increasing temperature and shear rate. A temperature-dependent Bingham constitutive equation was established, achieving precise prediction of rheological behavior across the full temperature range from the non-Newtonian to the Newtonian regime. This study elucidates the spatiotemporal evolution of heavy oil rheological behavior throughout the entire CO 2 -thermal synergistic extraction process, providing a key theoretical tool for accurate prediction of development performance and dynamic regulation of production parameters.
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