化学
烯丙基重排
钯
催化作用
原子经济
组合化学
立体选择性
有机化学
作者
Chuan‐Jun Lu,Dongkai Chen,Hong Chen,Hong Wang,Hongwei Jin,Xifu Huang,Jianrong Gao
摘要
A method for the allylic amidation of tautomerizable heterocycles was developed by a palladium catalyzed allylation reaction with 100% atom economy. A series of structurally diverse N-allylic substituted heterocycles can be synthesized in good yields with high chemo-, regio-, and stereoselectivities under mild conditions.
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