Plasma-assisted degradation of a short-chain perfluoroalkyl substance (PFAS): Perfluorobutane sulfonate (PFBS)

This study investigates the degradation of perfluorobutane sulfonate (PFBS), a chemical compound belonging to a group of per- and polyfluoroalkyl substances (PFAS), by gas-phase electrical discharge plasma. Plasma alone was ineffective in degrading PFBS due to its poor hydrophobicity, which inhibited the compound from accumulating at the plasma-liquid interface, the region of chemical reactivity. To overcome bulk liquid mass transport limitations, a surfactant, hexadecyltrimethylammonium bromide (CTAB), was introduced to interact with and transport PFBS to the plasma-liquid interface. In the presence of CTAB, ~99% of PFBS was removed from the bulk liquid and concentrated at the interface, where 67% of the concentrate was degraded and 43% of that amount was defluorinated within one hour. PFBS degradation was further improved by optimizing the surfactant concentration and dosage. Experiments with a range of cationic, non-ionic, and anionic surfactants revealed that the PFAS-CTAB binding mechanism is predominantly electrostatic. A mechanistic understanding of the PFAS-CTAB complex formation, its transport to and destruction at the interface is proposed, alongside the chemical degradation scheme, which includes the identified degradation byproducts. This study shows that surfactant-assisted plasma treatment is one of the most promising techniques for destroying short-chain PFAS in contaminated water.