Core–Sheath Heterogeneous Interlocked Conductive Fiber Enables Smart Textile for Personalized Healthcare and Thermal Management

Abstract Whereas thermal comfort and healthcare management during long‐term wear are essentially required for wearable system, simultaneously achieving them remains challenge. Herein, a highly comfortable and breathable smart textile for personal healthcare and thermal management is developed, via assembling stimuli‐responsive core–sheath dual network that silver nanowires(AgNWs) core interlocked graphene sheath induced by MXene. Small MXene nanosheets with abundant groups is proposed as a novel “dispersant” to graphene according to “like dissolves like” theory, while simultaneously acting as “cross‐linker” between AgNWs and graphene networks by filling the voids between them. The core–sheath heterogeneous interlocked conductive fiber induced by MXene “cross‐linking” exhibits a reliable response to various mechanical/electrical/light stimuli, even under large mechanical deformations(100%). The core–sheath conductive fiber‐enabled smart textile can adapt to movements of human body seamlessly, and convert these mechanical deformations into character signals for accurate healthcare monitoring with rapid response(440 ms). Moreover, smart textile with excellent Joule heating and photothermal effect exhibits instant thermal energy harvesting/storage during the stimuli‐response process, which can be developed as self‐powered thermal management and dynamic camouflage when integrated with phase change and thermochromic layer. The smart fibers/textiles with core–sheath heterogeneous interlocked structures hold great promise in personalized healthcare and thermal management.