Interface deciphering for highly interfacial adhesion and efficient heat energy transfer

Interfacial adhesion and interfacial thermal resistance (ITR) are two critical factors in the interfacial force and energy transfer, but it is difficult to simultaneously achieve the desirable interfacial adhesion and ITR. Here, we overcome this challenge by fabricating an elastomer composite consisting of polydimethylsiloxane (PDMS) and micro-scale spherical aluminum (Al) fillers, which offers the high adhesion strength (1.28 MPa), high interfacial adhesion energy (528.4 J/m2), and low ITR (0.028 mm2·K/W) between the PDMS/Al elastomer composite and substrates. We further propose a quantified physical model to establish the relationship between interfacial adhesion and ITR for low phonon mismatch interfaces. This work will contribute to the development of interface science and guide the regulation of force and energy transfer at interface for wide range applications, such as electronic packaging, thermal storage, sensors, and medicine.