材料科学
超级电容器
枝晶(数学)
双金属片
电极
功率密度
导电体
电化学
储能
复合材料
纳米技术
金属
冶金
功率(物理)
物理化学
物理
化学
量子力学
数学
几何学
作者
Chenya Ruan,Dongdong Zhu,Jiqiu Qi,Qingkun Meng,Fuxiang Wei,Yaojian Ren,Yanwei Sui,Hao Zhang
标识
DOI:10.1016/j.surfin.2021.101274
摘要
Bimetallic transition metal sulfides (TMSs) and MXene are the two kinds of promising candidates as electrode materials for supercapacitors based on different storage mechanisms. However, little work has been performed on their composites. In this paper, Ti3C2 MXene-wrapped CoNi2S4 nanotrees were synthesized controllably using flake ZIF-67 as precursor grown on nickel foam, which was transformed into dendrite CoNi2S4 dendrite in MXene suspension (weak acidic environment). The formation mechanism of CoNi2S4 dendrite was discussed. Ti3C2 MXene-wrapped CoNi2S4 nanotrees delivered very high specific capacity of 933 C g−1 at 1 A g−1 and good rate performance. This is due to that the unique dendrite morphology can provide many exposed electro-active sites and wrapped conductive MXene can facilitate the charge transfer. An asymmetric supercapacitor was assembled using CoNi2S4/MXene/NF and RGO as positive and negative electrodes, which delivered a high energy density of 30.5 Wh kg−1 without deteriorating its high power density (1587 W kg−1). This device can power the clock for 55 minutes, demonstrating its broad practical application potential.
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