Polyoxometalate-based hydrogen-bonded organic frameworks as a new class of proton conducting materials

To develop new types of crystalline proton conducting materials for fuel cells, a polyoxometalate-based hydrogen-bonded organic framework (PHOF) based on Keggin-type [PMo₁₂O₄₀]³⁻ and phenylimidazole (PHOF 1) has been prepared.