流动电池
钒
氧化还原
循环伏安法
介电谱
电极
材料科学
电解质
电流密度
扫描电子显微镜
石墨
电化学
X射线光电子能谱
化学工程
分析化学(期刊)
化学
无机化学
复合材料
有机化学
物理化学
工程类
物理
量子力学
作者
Jing-Yu Xi,Wenguang Zhang,Zhaohua Li,Haipeng Zhou,Le Liu,Zenghua Wu,Xinping Qiu
出处
期刊:International Journal of Electrochemical Science
[ESG]
日期:2013-04-01
卷期号:8 (4): 4700-4711
被引量:37
标识
DOI:10.1016/s1452-3981(23)14633-5
摘要
Electro-oxidation method is used to improve the electrolyte accessibility and reaction activity of the graphite felt (GF) electrode for vanadium redox flow battery (VRB). The effect of electro-oxidation current density on activity of oxidized graphite felt (OGF) is investigated and the optimized parameter is suggested. Scanning electron microscope result indicates that the surface of GF is etched and becomes rougher by electro-oxidation treatment. Cyclic voltammetry and electrochemical impedance spectroscopy results show that the OGF obtained at 50 mA/cm2 (OGF-50) has the highest oxidation peak current density and lowest charge transfer resistance towards VO2+/VO2+ redox reaction, due to the introduction of surface oxygen-containing active functional groups, which is further verified by X-ray photoelectron spectroscopy. VRB single cell using OGF-50 electrode also exhibits the best cell performance, with a voltage and energy efficiency of 87% and 77% at 60 mA/cm2, respectively. Electro-oxidation method is environmentally friendly and controllable comparing with the tradition activation methods, such as concentrated acid treatment and high-temperature thermal treatment.
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