双折射
八面体
偏心因子
材料科学
结晶学
Crystal(编程语言)
金属
化学
晶体结构
光学
物理
计算机科学
冶金
程序设计语言
作者
Rui Zhang,Xin Su,Jie Zhang,Mingyao Xiong,Yineng Huang
出处
期刊:Dalton Transactions
[The Royal Society of Chemistry]
日期:2021-01-01
卷期号:50 (47): 17559-17565
被引量:3
摘要
The introduction of d0 transition metal Mo6+ cations into a phosphate generates a new acentric molybdophosphate, RbMo2P3O14. It shows uncommon [Mo2P3O14]∞ layers composed of isolated [MoO6] octahedra and [P3O10] groups. To the best of our acknowledge, it exhibits the largest birefringence (a calculated value of 0.166 at 546 nm) among reported molybdophosphates. In addition, it also possesses a shorter UV cut-off edge (about 250 nm) than other molybdates and molybdophosphates, indicating that it can be used as a birefringent crystal in the UV optical region. First-principles electronic structure analysis suggests that the large birefringence mainly originates from highly distorted [MoO6].
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