Enhanced Chemical Stability in the Twisted Dodecagonal Stacking of Two-Dimensional Copper Nanocluster Assemblies

Deterministic chemical stacking of two-dimensional materials with controlled symmetry is a synthetic chemistry challenge that deserves attention. It is plausible that depending on the angle of stacking the material properties of the assembly could be tuned. Herein, we report 30° twisted stacking of two-dimensional nanosheets of a hexagonal assembly of organic ligand-stabilized Cu nanoclusters formed through a Zn²⁺-mediated complexation reaction. Electron diffraction in transmission electron microscopy revealed the presence of regions of dodecagonal symmetry with the apparent loss of translation symmetry. Photoluminescence measurements indicated the formation of the stacked assembly in the liquid medium. The as-synthesized twisted stacking structure exhibited superior delayed photoluminescence and chemical stability─in the presence of molecular iodine─as compared to the hexagonal crystal. The discovery can lead to a bright future in exploring new chemical and physical properties through the design of stacked assemblies of luminescent or other materials.