胺化
化学
降冰片烯
催化作用
反应条件
组合化学
反应机理
有机化学
聚合
聚合物
作者
Bo‐Sheng Zhang,Yuke Li,Xue‐Ya Gou,Zhe Zhang,Yang An,Xingang Wang,Yong‐Min Liang
摘要
This report described the first DMAP and PivOH-promoted ortho-C-H amination and ipso-allenization reaction of iodobenzenes realized by Pd/norbornene cooperative catalysis. Based on control experiments and DFT calculations, we speculated that the three ligands have different functions and mechanism paths in the reaction.
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