电致发光
材料科学
热稳定性
光致发光
循环伏安法
带隙
差示扫描量热法
杂蒽
发光
薄膜
热重分析
有机半导体
兴奋剂
芴
有机电子学
有机发光二极管
分析化学(期刊)
电化学
光电子学
光化学
聚合物
纳米技术
化学
物理化学
有机化学
电极
复合材料
物理
图层(电子)
晶体管
电压
量子力学
热力学
作者
Changjin Ou,Zhenfeng Lei,Mingli Sun,Linghai Xie,Yan Qian,Xinwen Zhang,Wei Huang
标识
DOI:10.1016/j.synthmet.2014.12.034
摘要
The number of bulky groups in hindrance-capped π-systems is closely relative to thin film morphology, stability and luminescent features in printing electronics. Herein, we demonstrated advantages of dumbbell-shape over mono-substituted organic semiconductors by designing two highly bulky 3′,6′-bis(octyloxy) spiro[fluorene-9,9′-xanthene] (OSFX)-functionalized pyrene derivatives, OSFXPy and DOSFXPy. Their differences in terms of thermal, photophysical and electrochemical properties, and film morphologies were characterized via thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), UV–vis absorption and photoluminescence (PL), cyclic voltammetry and atomic force microscopy (AFM). DOSFXPy has higher thermal and electrochemical stability, more suitable energy levels and smaller bandgap than that of OSFXPy. Thin film of DOSFXPy is smooth and pin-hole free, while OSFXPy is easy to crystallize and form large crystal domains. Solution-processed nondoped electroluminescent devices based on DOSFXPy exhibit stable deep-blue emission with excellent CIEx,y color coordinates (x = 0.15, y = 0.13) at the luminance of 1000 cd/m2, and the maximum luminance of up to 3200 cd/m2 and maximum current efficiency of 2.07 cd/A, respectively. Moreover, solution-processed doped OLEDs with DPAVBi show greenish-blue emission with optimum current efficiency of 4.52 cd/A at doping concentration of 3 wt%.
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