四甲基铵
卤化物
化学
氘
红外线的
红外光谱学
水溶液
分子
离子
谱线
氢键
无机化学
氢
波数
物理化学
分析化学(期刊)
光化学
原子物理学
光学
有机化学
物理
天文
标识
DOI:10.1366/0003702904087244
摘要
Infrared spectra of tetramethylammonium (TMA) halides are discussed with an emphasis on perturbations of the hydrogen vibrational motions caused by anion effects in aqueous solution. The fully deuterated molecule is included in the discussion. The effect of halide anion concentration on the C-H stretching region of the IR spectrum is presented. It is concluded that hydrogen bonding is not the cause of the shift of the wavenumber of these modes.
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