材料科学
吸附
肺表面活性物质
临界胶束浓度
接触角
奈奎斯特图
缓蚀剂
分析化学(期刊)
动态光散射
腐蚀
表面张力
化学工程
电化学
热力学
胶束
物理化学
水溶液
化学
复合材料
有机化学
纳米颗粒
介电谱
电极
纳米技术
工程类
物理
作者
Fu Zhang,Xianghong Li,Shuduan Deng,Min Tang,Guanben Du
标识
DOI:10.1016/j.jmrt.2021.11.107
摘要
The inhibition effect of amphoteric surfactant of octadecyl dimethyl betaine (BS-18) on cold rolled steel (CRS) in H3PO4 solution was studied by weight loss, electrochemical technique, surface analysis and quantum chemical calculations. The results show that BS-18 acts as an efficient inhibitor on CRS in 1.0 M H3PO4 medium at 20–50 °C, and the maximum inhibition efficiency is 87.1% with 50 mg L−1 at 20 °C. Its adsorption on steel surface obeys Langmuir adsorption isotherm, which is endothermic process accompanying with the increase of entropy. Compared with uninhibited solution, apparent activation energy, pre-exponential factor, activation enthalpy and activation entropy become higher in inhibited solution, while both reaction constant and rate constant decrease after adding BS-18. Inhibition performance remains more stable from 3 to 48 h, and fluctuates slightly with the acid concentration from 0.5 to 5.0 M. BS-18 is a mixed-type inhibitor through “geometric blocking effect”. EIS is a time constant with one depressed capacitive loop in Nyquist plot and one phase angle in Bode phase plot, and the charge transfer resistance turns to become more larger in the presence of BS-18. SEM and AFM micrographs of inhibited CRS surface appear little corrosion, and its contact angle is increased. There are functional groups of C–N and C–N+ in the adsorptive film of BS-18 on CRS surface using XPS analysis. Critical micelle concentration (CMC) of BS-18 is about 20 mg L−1 from surface tension measurements. Quantum chemical calculations confirm that the active adsorption site of BS-18 is the hydrophilic group of N+ and –CH2COO−.
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