单体
二甲氧基甲烷
聚合物
三氟乙酸
高分子化学
聚合
微型多孔材料
基础(拓扑)
化学
材料科学
化学工程
有机化学
催化作用
数学
工程类
数学分析
作者
Mariolino Carta,Richard Malpass‐Evans,Matthew Croad,Yulia Rogan,Michael Lee,Ian Rose,Neil B. McKeown
出处
期刊:Polymer Chemistry
[The Royal Society of Chemistry]
日期:2014-06-20
卷期号:5 (18): 5267-5272
被引量:105
摘要
A step-growth polymerisation based on the formation of Tröger's base, performed by simple reaction of a suitable aromatic diamine monomer with dimethoxymethane in trifluoroacetic acid, provides polymers of high average molecular mass. The properties of the resulting polymers can be tailored by the choice of monomer. In particular, the Tröger's base polymerisation is highly suited to the preparation of soluble polymers of intrinsic microporosity (PIMs) due to the resulting fused-ring TB linking group, which is both highly rigid and prohibits conformational freedom.
科研通智能强力驱动
Strongly Powered by AbleSci AI