Deconstruction Engineering of Lignocellulose Toward High‐Plateau‐Capacity Hard Carbon Anodes for Sodium‐Ion Batteries

Abstract Biomass‐derived hard carbon is a promising anode material for commercial sodium‐ion batteries due to its low cost, high capacity, and stable cycling performance. However, the intrinsic tight lignocellulosic structure in biomass hinders the formation of sufficient closed pores, limiting the specific capacity of obtained hard carbons. In this contribution, a mild, industrially mature pretreatment method is utilized to selectively regulate biomass components. The hard carbon with a rich closed pore structure is prepared by optimizing the appropriate ratio of biomass composition. Optimized etching conditions enhanced the closed pore volume of hard carbon from 0.15 to 0.26 cm 3 g −1 . Consequently, the engineered hard carbon exhibited excellent electrochemical performance, including a high reversible capacity of 346 mAh g −1 with a high plateau capacity of 254 mAh g⁻¹ at 50 mA g⁻¹, robust rate capability, and cycling stability. The optimized hard carbon shows an 88 mAh g⁻¹ increase in plateau capacity compared to hard carbon from directly carbonizing bamboo fibers. This mature approach provides an easy‐to‐operate industrial pathway for designing high‐capacity biomass‐based hard carbons for sodium‐ion batteries.