Process analysis of microplastic aging during the photochemical oxidation process and its effect on the adsorption behavior of dissolved organic matter

Information on microplastics (MPs) interactions with dissolved organic matter (DOM) is essential for understanding their environmental impacts. However, research is scarce regarding the adsorption behavior of DOM with different characteristics onto pristine and aged MPs. This research thus investigates MPs aging behavior accelerated by UV/Persulfate and UV/chlorine oxidation processes and the adsorption behavior of organic matter with low-specific ultraviolet absorbance (L-SUVA) and high-SUVA (H-SUVA) characteristics. MPs were degraded by UV/Cl and UV/Persulfate for 30 days. Changes in thermal properties, surface morphology, and chemistry were studied using different analytical techniques. The adsorption behavior was assessed by adsorption kinetic and isotherm study. After oxidation the surface of the MPs showed a significant increase in the oxygen-containing functional groups, contact angle, surface roughness, and surface energy, and a decrease in crystallinity. The oxidation effect follows the order of UV/Cl > UV/Persulfate. The kinetic and equilibrium data of H-SUVA adsorption on pristine and aged MPs well-fitted the pseudo-second-order and Langmuir model. In contrast, L-SUVA well-fitted the pseudo-first-order and Freundlich model. The adsorption capacity (qm) increased in the following orders: 8.11 > 5.87>4.29 mg g−1 for H-SUVA and 19.81 > 6.662>5.315 mg g−1 for L-SUVA by MPs aged with UV/Cl, UV/Persulfate and pristine MPs, respectively. The larger the surface damage of MPs, the greater the adsorption affinity of DOM. The result was attributed to the physical adsorption process, hydrophobic interactions, electrostatic, hydrogen, and halogen bonding. These findings are beneficial to provide new insights involving the adsorption behavior and interaction mechanisms of DOM onto MPs for the environmental risk assessment.