分析化学(期刊)
X射线光电子能谱
傅里叶变换红外光谱
循环伏安法
电极
扫描电子显微镜
光谱学
检出限
材料科学
电化学气体传感器
电化学
化学
价(化学)
化学工程
物理化学
色谱法
量子力学
物理
工程类
复合材料
有机化学
作者
Thị Kim Ngân Nguyên,Tien Hung Nguyen,Ba Manh Nguyen,Hoang Anh Nguyen,Thi Thu Ha Vu,Quoc Hung Le,Quang Hai Tran,Thi Hai Yen Pham
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2023-05-01
卷期号:170 (5): 056505-056505
被引量:1
标识
DOI:10.1149/1945-7111/acced6
摘要
The study reports the development of a nanostructured mixed-valence Fe(II)Fe(III)BTC metal-organic framework (BTC = 1, 3, 5-benzenetricarboxylate) modified carbon paste electrode as a novel sensor for the amoxicillin detection in aqueous solutions using square wave voltammetry. The physicochemical properties of FeBTC were characterized using X-ray diffraction spectroscopy, Fourier-transform infrared spectroscopy, Brunauer–Emmett–Teller analysis, electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy. These techniques revealed that FeBTC has a surface area of 1211 m 2 g −1 , a total pore volume of 1.46 cm 3 g −1 , particle sizes ranging from 10 to 20 nm, and a mixed-valence structure. Furthermore, SEM, TEM, and energy-dispersive X-ray spectroscopy exhibited the homogeneous distribution of FeBTC throughout the modified electrode. The electrochemical study showed that the mixed-valence FeBTC improved the electron transfer capabilities of the electrode. Under optimal conditions, the modified electrode exhibited a significant increase in peak height compared to the unmodified electrode (4.6 times higher), with an acceptable reproducibility of 4.88% relative standard deviation. The linear range of the sensor was 1–100 μ M with a good coefficient of determination of 0.9985, and a detection limit of 0.107 μ M. Additionally, the sensor demonstrated excellent performance with the satisfactory recoveries and a good correlation with LC-MS/MS analysis.
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