催化作用
氨
镍
产量(工程)
化学
等离子体
氨生产
分子
金属
无机化学
氢
非热等离子体
化学工程
材料科学
有机化学
冶金
工程类
物理
量子力学
作者
Javishk Shah,Ting Wu,Jolie Lucero,Moisés A. Carreón,Maria L. Carreon
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2018-11-22
卷期号:7 (1): 377-383
被引量:77
标识
DOI:10.1021/acssuschemeng.8b03705
摘要
Herein, we demonstrate a synergistic approach with radiofrequency plasma to synthesize ammonia in the presence of Ni-MOF-74 as catalyst. The Ni-MOF displayed higher ammonia yields as compared to the pure Ni metal. Specifically, ammonia yields as high as 0.23 g-NH3 (g-catalyst·kWh)−1 and energy cost of 265 MJ mol–1 over Ni-MOF were observed. The enhanced catalytic activity of the Ni-MOF in the presence of plasma was attributed to the presence of pores, which improved mass transfer of guest and product molecules during reaction, the presence of open Ni metal sites, and lower surface hydrogen recombination. Furthermore, the ammonia energy yield of our plasma-Ni MOF catalyst is superior to those of the state-of-the-art RF plasma catalytic systems.
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