Palladium‐Catalyzed C–H Arylation of Amides by Triazole Assistance

Versatile palladium‐catalyzed C–H arylations of benzamides were accomplished with the assistance of a removable triazole amine (TAM). The robustness of the palladium‐catalyzed C–H functionalization protocol is reflected in its broad functional group tolerance, ample substrate scope, and ability to proceed under silver‐free reaction conditions.