过电位
催化作用
材料科学
氢
制氢
异质结
氢燃料
工作(物理)
纳米技术
分解水
化学工程
电化学
光催化
物理化学
热力学
光电子学
有机化学
物理
化学
工程类
生物化学
电极
作者
Jue Hu,Chengxu Zhang,Peng Yang,Jingyi Xiao,Tao Deng,Yong Li,Bolong Huang,Michael K.H. Leung,Shihe Yang
标识
DOI:10.1002/adfm.201908520
摘要
Abstract As a prerequisite for a sustainable energy economy in the future, designing earth‐abundant MoS 2 catalysts with a comparable hydrogen evolution catalytic performance in both acidic and alkaline environments is still an urgent challenge. Decreasing the energy barriers could enhance the catalysts' activity but is not often a strategy for doing so. Here, the first kinetic‐oriented design of the MoS 2 ‐based heterostructure is presented for pH‐universal hydrogen evolution catalysis by optimizing the electronic structure based on the simultaneous modulation of the 3d‐band‐offsets of Ni, Co, and Mo near the interface. Benefiting from this desirable electronic structure, the obtained MoS 2 /CoNi 2 S 4 catalyst achieves an ultralow overpotential of 78 and 81 mV at 10 mA cm −2 , and turnover frequency as high as 2.7 and 1.7 s −1 at the overpotential of 200 mV in alkaline and acidic media, respectively. The MoS 2 /CoNi 2 S 4 catalyst represents one of the best hydrogen evolution reaction performing ones among MoS 2 ‐based catalysts reported to date in both alkaline and acidic environments, and equally important is the remarkable long‐term stability with negligible activity loss after maintaining at 10 mA cm −2 for 48 h in both acid and base. This work highlights the potential to deeply understand and rationally design highly efficient pH‐universal electrocatalysts for future energy storage and delivery.
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