材料科学
腐蚀
介电谱
扫描电子显微镜
镁合金
能量色散X射线光谱学
模拟体液
合金
复合材料
冶金
电化学
化学
电极
物理化学
作者
Tao Zhu,Yi Yu,Jian Yang,Yongshui Shen,He Liuyong,Ying Xiong
标识
DOI:10.1016/j.matchemphys.2020.124039
摘要
Two specimens were prepared along the normal (ND) and transverse (TD) directions of the AZ80 magnesium alloy rolled sheet, respectively, and the other specimen was prepared along the normal direction at 45° (ND45). Three specimens (ND, ND45 and TD) were immersed in dynamic immersion equipment for in-situ electrochemical test. Electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to investigate the static and dynamic corrosion behavior of the specimens in simulated body fluid (SBF). The results indicated that the specimens with different orientations exhibited anisotropy of corrosion performance. The electrochemical corrosion resistance of the specimens decreased in the following order: TD > ND45 > ND. The electrochemical corrosion resistance of the specimens decreased with increasing flow rate. The specimens immersed in SBF solution suffered localized corrosion, and the corrosion degree at the edge position of the specimen was higher than that at the middle position in dynamic environment. Computational fluid dynamics (CFD) simulations showed that with the increase of flow rate, the increase of shear stress and mass transfer coefficient led to the intensification of localized corrosion. The effect of initial texture and flow rate on the corrosion behavior of magnesium alloy was discussed. Two specimens were prepared along the normal (ND) and transverse (TD) directions of the AZ80 magnesium alloy rolled sheet, respectively, and the other specimen was prepared along the normal direction at 45° (ND45). Three specimens (ND, ND45 and TD) were immersed in dynamic immersion equipment for in-situ electrochemical test. Electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to investigate the static and dynamic corrosion behavior of the specimens in simulated body fluid (SBF). The results indicated that the specimens with different orientations exhibited anisotropy of corrosion performance. The electrochemical corrosion resistance of the specimens decreased in the following order: TD > ND45 > ND. The electrochemical corrosion resistance of the specimens decreased with increasing flow rate. The specimens immersed in SBF solution suffered localized corrosion, and the corrosion degree at the edge position of the specimen was higher than that at the middle position in dynamic environment. Computational fluid dynamics (CFD) simulations showed that with the increase of flow rate, the increase of shear stress and mass transfer coefficient led to the intensification of localized corrosion. The effect of initial texture and flow rate on the corrosion behavior of magnesium alloy was discussed. - Electrochemical corrosion behavior of AZ80 magnesium alloy in dynamic SBF environment. - Corrosion resistance of materials with different initial orientations - CFD simulation of shear stress in flow field environment. - Effect of texture and flow rate on corrosion resistance.
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