Methyl-grafted silica nanoparticle stabilized water-in-oil Pickering emulsions with low-temperature stability

The viscosity of water-in-oil Pickering emulsions may dramatically increase upon cooling. The solvation of the long-chain alkyl groups grafted on the particles stabilizer is the likely cause of the strong dependence of rheological property on temperature. Thus, we hypothesize that silica nanoparticles (NPs) grafted with short-chain alkyl groups can stabilize Pickering emulsions, yielding weakly temperature-dependent rheological property. Using alkyl-grafted (methyl, octyl, and octadecyl) silica NPs as emulsifiers, the rheological properties and microstructure of the water-in-oil Pickering, as well as the solvation of the silica NPs, were studied using diffusing-wave spectroscopy microrheology measurements, confocal laser scanning microscopy, and low-field nuclear magnetic resonance measurements. The use of methyl- and octadecyl-grafted silica NPs, which have almost identical optimum contact angles, to stabilize emulsions dramatically reduced the effect of cooling on the viscosity. Moreover, the emulsions stabilized by these methyl-grafted silica NPs exhibited nearly constant rheological properties as the temperature decreased from 75 to 5 °C. The nearly constant rheological properties are attributed to the nearly constant solvation in this temperature range. These materials have potential applications in the cosmetics and petroleum industries.