纤维素
微晶纤维素
材料科学
溶解
纳米复合材料
离子液体
化学工程
再生纤维素
复合材料
化学
有机化学
工程类
催化作用
作者
Jinming Zhang,Nan Luo,Xiaoyu Zhang,Lili Xu,Jin Wu,Jian Yu,Jiasong He,Jun Zhang
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2016-06-24
卷期号:4 (8): 4417-4423
被引量:89
标识
DOI:10.1021/acssuschemeng.6b01034
摘要
All-cellulose nanocomposites, with cellulose nanocrystals as the reinforcing phase and regenerated cellulose as the matrix, are prepared by a partial dissolution method in 1-ally-3-methylimidazolium chloride (AmimCl), followed by solution casting. The direct images of many undissolved nanocrystals in cellulose/AmimCl solutions have been observed clearly by conventional transmission electron microscopy (TEM). X-ray diffraction (XRD) also proves that there are original cellulose I crystals in regenerated cellulose films. The nanocomposite films are compact, isotropic and transparent to visible light, and show good mechanical properties as a result of the nanocrystals reinforcement. Using microcrystalline cellulose (MCC) as the raw material, the optimal tensile strength and elastic modulus of nanocomposite films have reached 135 MPa and 8.1 GPa, respectively, by controlling the dissolution temperature and time. This work provides an easy and effective pathway to prepare all-cellulose composites.
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