The effects of PVA concentration, spin voltage and solidification distance on electrospinning were studied. It was found that PVA concentrations in the ranges of 5 %~ 8 %, spin voltage between 6.6~ 15 kV, solidification distance within 5 ~ 15 cm were suitable for electrospinning. Three kinds of PVA blend ing solutions, namely PVA/SA with 8 % / 0.5 %~1 %, PVA/SS with 8 % /2 %~4 % and PVA/CS with 8 % /2 %~3.5 % were suitable for the electrospinning and could produce nanofibers with good shape.