化学
电子转移
过渡金属
电子结构
催化作用
分子轨道
电子组态
光化学
长石
计算化学
分子
有机化学
氧化物
离子
作者
Ying Zhao,Shixuan Chen,Hang Qie,Shishu Zhu,Changyong Zhang,Xueyan Li,Wei Wang,Jun Ma,Zhiqiang Sun
出处
期刊:Water Research
[Elsevier]
日期:2023-06-01
卷期号:236: 119957-119957
被引量:17
标识
DOI:10.1016/j.watres.2023.119957
摘要
Radical and non-radical oxidation pathways have been universally validated in transition metals (TMs) oxides activated peroxymonosulfate (PMS) processes. However, achieving high efficiency and selectivity of PMS activation remains challenging due to the ambiguous tuning mechanism of TMs sites on PMS activation in thermodynamic scope. Herein, we demonstrated that the exclusive PMS oxidation pathways were regulated by d orbital electronic configuration of B-sites in delafossites (CuBO2) for Orange I degradation (CoIII 3d6 for reactive oxygen species (ROSs) vs. CrIII 3d3 for electron transfer pathway). The d orbital electronic configuration was identified to affect the orbital overlap extent between 3d of B-sites and O 2p of PMS, which induced B-sites offering different types of hybrid orbital to coordinate with O 2p of PMS, thereby forming the high-spin complex (CuCoO2@PMS) or the low-spin complex (CuCrO2@PMS), on which basis PMS was selectively dissociated to form ROSs or achieve electron transfer pathway. As indicated by thermodynamic analysis, a general rule was proposed that B-sites of less than half-filled 3d orbital tended to act as electron shuttle, i.e., CrIII (3d3), MnIII (3d4), interacting with PMS to execute an electron transfer pathway for degrading Orange I, while B-sites of between half-filled and full-filled 3d orbital preferred to be electron donator, i.e., CoIII (3d6), FeIII (3d5), activating PMS to generate ROSs. These findings lay a foundation for the oriented design of TMs-based catalysts from the atomic level according to d orbital electronic configuration optimization, as so to facilitate the achievement of PMS-AOPs with highly selective and efficient remediation of contaminants in water purification practice.
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