Azopyridine Polymers in Organic Phase Change Materials for High Energy Density Photothermal Storage and Controlled Release

Abstract Azo‐compounds molecules and phase change materials offer potential applications for sustainable energy systems through the storage and controllable release photochemical and phase change energy. Developing novel and highly efficient Azo‐based solar thermal fuels (STFs) for photothermal energy storage and synergistic cooperation with organic phase change materials present significant challenges. Herein, three types of ( ortho ‐, meta ‐, and para ‐) azopyridine polymers hinged with flexible alkyl chain are synthesized, in which meta ‐azopyridine polymer exhibits striking photothermal storage capacity of 430 J/g, providing a feasibility solution for developing high energy density Azo‐based STFs. Furthermore, a stable two‐phase hybrid system was innovatively constructed by combining the meta ‐azopyridine polymer with organic phase change materials leveraging hydrogen bonds and van der Waals interactions to collectively harness phase change energy and photothermal energy. The organic phase change material not only supplies additional phase change latent heat but also serves as a solvent, offering abundant free volume for the photo‐induced isomerization of the azopyridine chromophores, which successfully circumvents the low charging efficiency in the condensed state and reliance on solvent‐assisted charging in traditional Azo‐based STFs. This study demonstrates the energy distribution and utilization for household consumers and the photothermal‐assisted insulation strategy, achieving more extensive potential implementation for STFs.