潜热
材料科学
相变材料
热导率
热能储存
过冷
复合数
赤藓糖醇
石墨
温度循环
化学工程
相变
热力学
复合材料
热的
化学
物理
食品科学
工程类
作者
Kening Yan,Lin Qiu,Yanhui Feng
标识
DOI:10.1016/j.est.2023.107667
摘要
Organic phase change materials possess the merits of high latent heat storage, small temperature changes, high chemical/thermal stability, low corrosion and reusability, and thus have attracted extensive attention in the research of low and medium-temperature energy storage media. However, pure phase change material has the deficiency of low thermal conductivity and easy leakiness, which seriously hinder their practical large-scale applications. In this work, the expanded graphite was used as the skeleton to encapsulate erythritol to form the composite phase change material. The composite had remarkably boosted thermal conductivity (5.97 ± 0.30 W/m·K compared with pure erythritol of 0.60 ± 0.03 W/m·K) and high melting latent heat (290.52 J/g) and solidification latent heat (239.52 J/g) at a loading rate of 95 wt%. The supercooling degree was reduced from 92.41 °C to 43.75 °C, facilitating the release of latent heat. The developed composite phase change material exhibits extraordinary heat transfer and storage characteristics, which has great application prospects in the fields of solar photothermal conversion utilization.
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