四氢呋喃
特里斯
化学
氧化物
环境科学
有机化学
溶剂
生物化学
作者
James Kakoullis,Frank R. Fronczek,Andrew W. Maverick
标识
DOI:10.1107/s1600536813020059
摘要
The title compound, C21H15O4P·0.5C4H8O, contains an ordered phosphane oxide in a general position and a tetra-hydro-furan solvent mol-ecule disordered about a twofold axis. All three aldehyde substituents are nearly coplanar with their attached benzene rings, with C-C-C-O torsion angles in the range 1.64 (17)-4.24 (19)°. All three have different conformations with respect to the P=O group, one syn, one anti, and one gauche. Two of the aldehyde substituents form inter-molecular C-H⋯O contacts.
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